Ethanol Extraction: Explained
Ethanol extraction is a popular method for producing high-quality botanical extracts across various industries. This guide will cover how this method works, its benefits, and key considerations to help you decide if it’s the right method for your operation.
What is Ethanol Extraction?
Ethanol extraction involves using ethanol as a solvent to efficiently extract compounds from plant materials. This method is widely valued for its efficacy in extracting essential oils, natural flavors, and botanical ingredients. By soaking the raw materials in ethanol, desired compounds like oils, terpenes, and active ingredients are dissolved and collected, resulting in a concentrated extract ready for further refinement.
How Does it Work?
Ethanol extraction uses a straightforward process of combining ethanol with biomass to pull out valuable compounds. Here’s a closer look at the key steps:
Soak Time and Temperature Control
Optimizing both soak time and evaporation temperature is crucial for achieving high-quality extracts. Shorter soak times can result in a cleaner extract, while longer soak times may increase yields but pull more unwanted compounds.
Ethanol Extraction Soak Time
The optimal soak time varies depending on the type of plant material and the target compounds. Generally, a soak time of a few minutes to an hour is sufficient to extract the desired compounds while minimizing impurities.
Ethanol Evaporation Temperature
After extraction, efficiently removing the ethanol is crucial. The ideal evaporation temperature is around 70-80°C (158-176°F) to ensure complete removal without degrading the extracted compounds.
Ethanol Extraction of THC
This extraction method is particularly effective for extracting THC due to its high solvation power. It can pull both cannabinoids and terpenes from the plant, resulting in a full-spectrum extract. However, this method may also extract unwanted compounds like fats and waxes, which can require additional purification steps.
When using this method to extract THC, the process can be modified to isolate specific cannabinoids or create full-spectrum products, depending on your end product goals. However, to prevent contamination, care must be taken to ensure that any residual ethanol is thoroughly removed, especially if denatured ethanol is used.
Benefits of This Method
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PROS | CONS |
---|---|
Efficient: Ethanol extraction tends to have a high throughput overall. | Costly: Ethanol is approximately 5.5 times the price of CO2 and has much more costly operational cost. |
GRAS: “Generally Regarded As Safe” according to the FDA. | Risk of Contamination: Chemical denaturants are intended to prevent human consumption; yet, they still find their way into cannabinoid extracts. |
Powerful: Ethanol has a very high solvation power during extraction. | Volatile: Ethanol is a very flammable substance making it more dangerous to work with. |
Eliminate Winterization: Ethanol extraction accomplishes winterization | Less Selective: High solvation power negates the ability to selectively extract various compounds. |
Good for Full Spectrum: Extract full spectrum distillate with very little extra effort. | Can’t make shatter or “sauce”: Lack of selectivity means losing the capability to create specific products. |
Why Ethanol Extraction is More Costly for Business When Scaling
Though ethanol is a common extraction method in the hemp industry, it is undoubtedly a costlier method for an extraction company to utilize. Even the direct cost of each solvent is drastically different. For example, a pound of food grade ethanol when purchased in bulk is $4.71/lb at current price whereas a pound of food grade CO2 when purchased in bulk is about $0.04/lb at current price. Apart from this immediate cost, the overall process is shockingly more expensive as well.
Resources
Ethanol extraction is an extraction process that is typically run at low temperatures. The ethanol is cooled to below -20 degrees celsius before it’s introduced to hemp biomass. Cooling the ethanol reduces the amount of extracted chlorophyll and waxes. Accounting for the energy required to cool down the ethanol to such low temperatures and then evaporate after use, the overall energy cost for ethanol extraction is nearly 3 to 6 times the price of using a CO2 extraction process. Though this is a major factor in overall operating expenses, it is not the primary overhead cost of concern for a manufacturer who has chosen ethanol as their extraction method.
This extraction method requires an exorbitant amount of ethanol to be used for each pound of hemp. In reality, approximately 1 to 1.5 gallons of ethanol has to be used per pound of dry hemp biomass to extract the desired cannabinoids. Hemp is considered to be a very absorbent biomass material. Because of this, the ethanol used must saturate the plant material in order for an effective extraction to take place. For this reason a large volume of ethanol is needed to extract CBD out of hemp. With ethanol being $4.71/lb at current price, this creates a tremendous cost to extract with ethanol.
Solvent Recovery
Perhaps the key cost driver for ethanol extraction lies in solvent recovery. Though many ethanol extraction equipment businesses supply centrifuges or presses to get rid of the leftover ethanol in the biomass, even the best equipment will provide only a 90 to 95% recovery of their ethanol.
This creates a 5% to 10% loss in ethanol which is a massive cost driver for ethanol extraction. By way of example, suppose you wanted to process 1000 lb of hemp. If ethanol is your choice solvent for extraction, you will need 1000 gallons of ethanol to extract your desired cannabinoids. At a cost of roughly $16-$33/gallon of food grade ethanol, the upfront cost will range from $16,000 to $33,000. Even if you recovered 90% of the ethanol, the total loss will be $1,600 – $3,300 for each 1000 lbs extracted. If you are a manufacturer extracting 1000 lbs every day, this would be a daily operational cost for your business. In comparison, the same extraction method for the equivalent 1000 lbs of hemp using CO2 as a solvent would only result in roughly $70 per day – thousands of dollars difference compared to ethanol solvent loss.
Other Hidden Costs
Aside from these drastic cost differences due to energy and solvent loss, there are numerous hidden costs when using an ethanolic extraction method including insurance, facilities, testing and solvent reuse costs. It is, by far, more financially viable to decrease or eliminate these costs by using a CO2 extraction method instead.
CO2 vs. Ethanol Extraction Equipment Energy Costs
The primary difference between CO2 and ethanol extraction equipment is the cost of the extraction operations. CO2 equipment has a much lower cost to produce a kilogram of extract compared to ethanol. A lot of this has to do with overall energy costs of the extraction equipment used.
Processing a ton of hemp per day into extracts can be an energy-intensive process depending on how the hemp is extracted. The following table compares the energy expense for ethanol extraction equipment versus the energy expense for CO2 extraction equipment.
Energy Cost for Ethanol Extraction for 1 ton/day at 1 gal/lb of Hemp
18,711 | Liters to cool from 25ºC to -20ºC |
16,840 | Liters to heat & evaporate after ethanol loss |
454 | kW/hr to cool from 25ºC to -20ºC |
481 | kW/hr to heat to boiling point |
3,105 | kW/hr to evaporate |
4,040 | kW/hr total @ 100% efficiency |
75% | Efficiency |
5,387 | Total kW/hr |
$0.09 | Cost for kW/hr |
$506.36 | Cost per day ethanol extractors |
Energy Cost for CO2 Extraction for 1 ton/day Including Winterization
636 | Liters to cool from 25ºC to -20ºC |
636 | Liters to heat & evaporate after ethanol loss |
15 | kW/hr to cool from 25ºC to -20ºC |
18 | kW/hr to heat to boiling point |
117 | kW/hr to evaporate |
151 | kW/hr total @ 100% efficiency |
75% | Efficiency |
201 | Total kW/hr |
$0.09 | Cost for kW/hr |
$18.92 | Cost per day for winterization |
$43.20 | kW/hr per day CO2 extractors |
$3.88 | Cost per day CO2 extractors |